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  • 31
    Dec
    2012
    12:32pm, EST

    The science of Champagne bubbles up again for New Year's Eve

    Francois Nascimbeni / AFP - Getty Images

    French researcher Gerard Liger-Belair works on a glass of champagne in his laboratory in Reims, located in the Champagne region in eastern France.

    By Alan Boyle, Science Editor, NBC News

    Follow @b0yle


    If you really want to impress your bubbly-sipping friends tonight, be sure to chill a big bottle of Champagne to somewhere between 39 and 50 degrees Fahrenheit (4 to 9 degrees Celsius), bring out the narrow glasses (not those wide plastic cups!) and pour the stuff gently down the angled side of the glass like beer.

    This is the scientific way to treat Champagne sparkling wine, based on research conducted over the years by Gerard Liger-Belair, a physicist at the University of Reims in France's Champagne region. His studies on the behavior of bubbly — including high-speed photography of popping bubbles and infrared imaging of carbon dioxide flow — have made him the world's highest-profile expert on Champagne science.

    It's a tough job — but somebody's gotta do it.

    "I love the beauties behind bubble science," Liger-Belair said in an email. "Since I became a scientist, many people have remarked that I seem to have landed the best job in all of physics, since my research on bubbles requires that I work in a lab stocked with top-notch Champagne — and I'd be inclined to agree."


    For Liger-Belair and his colleagues, it's mostly about the bubbles. To be sure, there's much more to sparkling wine than the sparkle: As many as 80 different vintages of wine may be blended together to create one batch of Champagne using the traditional process. A small amount of yeast and sugar is added, and the bottles are sealed up for fermentation. Months later, the yeast sediment is blown out through the bottle's neck — and then the bottle is quickly corked up and wired shut.

    Liger-Belair's research focuses on what happens next, when the cork is popped off. The CO2 that was created through the fermentation process bubbles out of the wine — tickling the nose with a fizzy aerosol of alcohol and flavorful ingredients known as volatile organic compounds. The more CO2 that can be liberated after the champagne is poured into the glass, the better.

    That's where science comes into play. Liger-Belair and his colleagues recently reported that larger bottles of Champagne retain more CO2 in the wine as it's being poured into the glasses. So if you have a choice between several small bottles and fewer big bottles, go for the big ones. But be sure those bottles are well-chilled: Warm champagne loses its CO2 quickly as it's being poured, leaving less to fizz up out of the glass.

    Ray Isle, executive wine editor of Food & Wine, shares five ways to get the most out of your New Year's bubbly.

    Speaking of the glass: Liger-Belair's team determined that tall, narrow-rimmed flutes produce a better effect than the wide-rimmed "coupes" that folks more typically associate with sparkling wine. That's because the CO2 rises out of a wide-rimmed glass too quickly, over a wider surface area. Also, glass flutes are better than plastic cups, and not just for aesthetic reasons: The plastic material is hydrophobic — that is, liquid-repellent — which means the bubbles are more likely to adhere to the sides of the cup and less likely to contribute to a nice fizz.

    If you really want to get your fizz on, wash your glasses before the party and dry them with a towel rather than letting them air-dry: The microscopic fibers of cellulose that are left inside the glass actually contribute to bubble production. Some glass-makers add tiny scratches to their Champagne glasses to create pleasing patterns of bubbles, and you can feel free to experiment with the same technique. (Just not with the expensive glassware.)

    When it comes to the pouring, don't splash the Champagne straight down into the bottom of the glass. Instead, trickle it down the side, like beer. That preserves more of the carbon dioxide for the bubbles that rise while you're drinking the wine. "The beer-like way of serving champagne much less impacts its dissolved CO2 concentration than the Champagne-like way of serving it, and especially at low Champagne temperatures (4 degrees C and 12 degrees C)," Liger-Belair reported.

    Liger-Belair has laid out many more findings about Champagne in a decade's worth of research papers — and in his book, "Uncorked: The Science of Champagne," which is being updated with the latest revelations for a new edition. One of his recent papers, an 88-page survey written for the European Physical Journal, is available for free download today.

    Here's a sampling of sparkling facts: 

    • There are six bottles' worth of gaseous CO2 packed into every bottle of Champagne.
    • A significant amount of that CO2 leaks out of the bottle through the cork. Liger-Belair's study of Champagne bottled in the 1990s suggested that almost a third of the CO2 could be lost over the course of 15 years. "Because the size of bubbles is linked with the level of dissolved CO2 in Champagne, bubbles get thinner over time when Champagne ages," Liger-Belair said.
    • The higher the wine's temperature, the bigger the "pop" when the cork is released. That's because the CO2 pressure increases with temperature. Some folks might keep their Champagne warm to maximize the pop, but be careful: A popped cork can travel as fast as 50 mph (80 kilometers per hour). Every year, the American Academy of Opthalmology warns that sparkling-wine corks rank among the top holiday-related eye hazards — and provides tips for proper cork removal.
    • Only 5 percent of the pop goes toward the cork's kinetic energy. Most of the rest goes toward generating the popping sound's shock wave. The pattern of CO2 that's set loose when the cork is popped is similar to the mushroom cloud created by an exploding atom bomb.
    • If you see a white wisp of mist rising from a just-popped bottle, that's not carbon dioxide. That's a fog of ethanol and water vapor, triggered by the sudden drop in gas temperature when the pressure is released. (That's what's known as adiabatic expansion.) 

    It might seem frivolous to devote so much attention to the physics of fizz, but Liger-Belair said his research is about much more than your single bottle of bubbly on New Year's Eve.

    "In fact, bubbles are a fantastic example of bubble dynamics in general, and studies dealing with champagne bubbles can be extended to many other areas where bubbles play a role, in natural as well as industrial processes. For example, marine aerosols created by bursting bubbles behave like champagne's bursting bubbles. ... The scales are different, but the basic principles are identical," he said in his email.

    Liger-Belair's research at the University of Reims is generally funded by enological and agricultural programs in France and Europe — such as L'Association Recherche Oenologique Champagne et Universit

    é, which was created to boost the Champagne region's best-known industr

    y.

    Follow @CosmicLog

    "As far as champagne is concerned, 350 million bottles sold per year all over the world deserve particular attention. The job may seem fun indeed, as any job made with passion should be," Liger-Belair said. "I am aware that devoting so much energy to studying champagne bubbles may seem 'weird,' but the implications of bubble dynamics are universal."

    So just before you take a sip of cool, sparkling beverage from your towel-dried flute, raise a toast to Liger-Belair ... and the science of champagne.

    Update for 12:45 p.m. ET: Legend has it that the wide-rimmed, bowl-like champagne coupe was modeled after the breast of Marie Antoinette (or the Empress Josephine, or Helen of Troy ...), but Snopes.com says there's no truth to the legend. 

    More about the science of alcoholic drinks:

    • Sip some New Year's Eve science
    • How to pour that drink, scientifically
    • The why behind a wine's bouquet
    • Future happy hour with high-tech cocktails

    Alan Boyle is NBCNews.com's science editor. Connect with the Cosmic Log community by "liking" the log's Facebook page, following @b0yle on Twitter and adding the Cosmic Log page to your Google+ presence. To keep up with Cosmic Log as well as NBCNews.com's other stories about science and space, sign up for the Tech & Science newsletter, delivered to your email in-box every weekday. You can also check out "The Case for Pluto," my book about the controversial dwarf planet and the search for new worlds.

    4 comments

    I wonder how many people couldn't care less about your 14th Century religious zealot objections to Champagne? I'm getting wasted, and I'm doing it with $200 a bottle bubbly. Don't like it? Eat me.

    Show more
    Explore related topics: books, physics, champagne, science, featured, new-years-eve, whimsy
  • 30
    Dec
    2011
    10:47pm, EST

    Sip some New Year's Eve science

    EPFL via YouTube

    Scientists found that several factors were key to the fluid dynamics of wine swirling.

    By Alan Boyle, Science Editor, NBC News

    I don't advise playing any drinking games on New Year's Eve, but when scientists play with their drinks, the results can make for interesting cocktail-party conversation.

    Here's a recap of research relating to the physics and chemistry of liquids in a glass:

    Tweak your twirl: Swirling red wine in the glass aerates the vintage and facilitates the release of all those wonderful aromas that distinguish a Rothschild from rotgut. The ideal is to have one smooth wave breaking around the bowl of the glass, and this year physicists at the École Polytechnique Fédérale de Lausanne in Switzerland figured out the fluid dynamics of the perfect swirl.

    They used glasses of different shapes plus a healthy supply of cheap merlot to study the factors that determined the shape of the wave rolling around the glass. Three factors emerged, as described in this ScienceNOW summary: the ratio of the level of the wine poured in to the diameter of the glass; the ratio of the diameter of the glass to the width of the circular shaking; and the ratio of gravitational force pushing downward to the centrifugal force pushing outward.


    A smooth wave can be achieved in glasses of widely varying sizes, as long as the three ratios are preserved. To get a feel for the right level of slosh, study the video below. Be careful not to swirl too vigorously, though: The researchers found that when the merlot was accelerated at 40 percent of the force of gravity, the slosh turned into an unwelcome splash.

    This video analyzes the fluid dynamics of wine swirling.

    Watch on YouTube

    Baby your bubbly: French researchers reported last year that the best way to baby that New Year's Eve champagne is to pour it gently down the side of your glass. This is one kind of wine you don't want to slosh: If you do, a lot of the carbonated bubbles are released before you bring the glass to your lips. And it's the bubbles that make champagne so pleasurable. The researchers found that champagne is best served when it's cold (39 degrees Fahrenheit, or 3.8 degrees Celsius). Warmer temperatures cause faster CO2 loss. And besides, who wants to drink warm champagne?

    When it comes to serving champagne, narrow-mouthed flutes are currently preferred to wide. saucer-shaped glasses for similar reasons. The greater surface area of the saucer bowl leads to faster CO2 dissipation.

    The same research group found that smooth-walled flutes tend to tone down the bubbles in poured champagne, while scratches in the glass promote bubble nucleation. Some glassmakers intentionally put microscratches in the inner surface to create showier special effects. If you want to do something similar, try wiping the inside of the flute with a cloth towel; the tiny fibers that are left behind produce a similar effect on nucleation. This video from the American Chemical Society tells you more about the chemistry of champagne:

    The American Chemical Society explains the science of champagne.

    Watch on YouTube

    Shaken or stirred? Physics and chemistry often determine whether an alcoholic drink takes flight or flops, as Harvard physicists Naveen Sinha and David Weitz explain this month in a report on cocktail physics for PhysicsWorld (free access with registration).

    Straight shots of aquavit, vodka or other spirits are best served cold — zero degrees F, or -18 degrees C — because that reduces the burning sensation you get in the throat and chest when you toss the shot down the hatch. But low temperatures also make it harder to savor the taste and aroma of other ingredients, which is why mixed drinks are usually served at higher temperatures.

    A nice chill helps balance the taste of a gin martini, though. If it's anywhere close to room temperature, the gin tends to overwhelm the vermouth.

    Speaking of martinis, The Straight Dope provides some words of wisdom about the "shaken-vs.-stirred" debate. The way Cecil's pals tell it, a gin martini is best stirred, not shaken — because shaking dissolves more air into the mix, "bruising" the gin and supposedly giving the martini more of a bitter taste.

    On the other hand, a vodka martini (which some drinkers refuse to recognize as a martini at all) is best served as cold as possible, and shaking with ice is a more effective way to cool down the drink. Also, shaking breaks down the oils in the vermouth more completely. In case you've forgotten, Agent 007 James Bond preferred his martinis with vodka — and "shaken, not stirred." A decade ago, researchers found that shaking deactivates the hydrogen peroxide in a martini better than stirring does, producing more of an antioxidant effect. They concluded that "007's profound state of health may be due, at least in part, to compliant bartenders."

    If you're making a manhattan, don't follow 007's lead. Sinha and Weitz observe that "a manhattan, which contains whisky, vermouth and bitters, can become cloudy when shaken."

    "This results from small air bubbles introduced into the beverage while shaking, which are then stabilized by the bitters," they write. "A stirred manhattan, in contrast, is clear, which is why it is typically served stirred, not shaken, unlike James Bond's martinis."

    For more about the physics of mixology, including a high-tech recipe for a hot and cold gin fizz, check out the full report from Physics World. Whatever you do, drink responsibly ... and have a happy and safe New Year's Eve.

    More about the science of alcoholic drinks:

    • The high-tech cocktail: Future happy hour is now!
    • Eight ancient drinks uncorked by science
    • How to pour that drink, scientifically
    • The why behind a wine's bouquet

    Alan Boyle is msnbc.com's science editor. Connect with the Cosmic Log community by "liking" the log's Facebook page, following @b0yle on Twitter and adding the Cosmic Log page to your Google+ presence. You can also check out "The Case for Pluto," my book about the controversial dwarf planet and the search for new worlds.

    14 comments

    Science and drinking! Cheers to both! BTW, I saw you on the Nightly News the other night!

    Show more
    Explore related topics: drinks, science, alcohol, featured, new-years-eve

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